In first trace prominent peaks (002), (200) and (201) were indexed to the hexagonal structure of CdS quantum dots. 415424, 1982. The band-gap (E 5 and 6), and so the content of CdS in tissues decreased with time extension. It was reported that the high-level accumulation of nanoparticles in the organs depended on the rapid capture of the reticuloendothelial system (RES), and RES capture occurred via opsonization, i.e., opsonins binding to nanoparticles in the plasma via recognition by phagocytes in the RES [24, 25]. Therefore, in this work, the toxicity and potential application of raw cadmium sulfide nanoparticles (CdS) in vivo were further studied through ICP-OES and CTs. Y. Li, L. Tang, S. Peng, Z. Li, and G. Lu, Phosphate-assisted hydrothermal synthesis of hexagonal CdS for efficient photocatalytic hydrogen evolution, CrystEngComm, vol. Provided by the Springer Nature SharedIt content-sharing initiative, Over 10 million scientific documents at your fingertips, Not logged in The crystal data used in the quantitative phase analysis are given in Table 1 for the cubic and hexagonal phases of CdS, respectively [23, 24]. S. R. Strzenbaum, M. Hckner, A. Panneerselvam et al., Biosynthesis of luminescent quantum dots in an earthworm, Nature Nanotechnology, vol. The rGO was then assembled on the CdS nanoparticles using a dip-coating method. AZoM, viewed 18 March 2023, https://www.azom.com/article.aspx?ArticleID=5816. In addition, the accumulation of CdS in the pancreas was found firstly, and authors gave a detailed discussion about this point. Small peaks at 345 and 368cm1 become stronger for the samples grown with higher Cd salt content and could be associated with an increase in the structural disorder of the particles. Although the cathode is commonly changed, carbon allotropes can also be employed in fabricating anodes. Sci. M. Zapata Torres thanks the hospitality of Dr. J. L. Pea Chapa during his sabbatical leave. Disulfide bond-reducing molecules, such as dithiothreitol (DTT) and mercaptoethanol (ME) were used as release triggers for controlled drug delivery from MCM-41 mesoporous nanospheres. Impact of carbon nanomaterials on the formation of multicellular spheroids by Bombax ceiba thorn extract mediated synthesis of silver nanoparticles, eva Bombax ceiba thorn extract mediated synthesis of silver nanoparticles: Eva Synthesis and characterization of Silver Nanoparticles. 1, Article ID 013708, 2006. Therefore, authors thought that CdS could enter into and damage the liver after exposure to mice, and parts of CdS might enter into the bile duct with bile, and then further into the duodenum. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. Oh SH, Lim SC (2006) A rapid and transient ROS generation by cadmium triggers apoptosis via caspase-dependent pathway in HepG2 cells and this is inhibited through N-acetylcysteine-mediated catalase upregulation. CdS nanoparticles have been synthesized using two mechanochemical approaches: acetate route (aCdS) [ 35] and combined mechanochemical synthesis (cCdS), where sulfur prepared in situ should enter the formation of cadmium sulfide [ 38 ]. Sol. 143, 249 (2011), M. Sathish, B. Viswanathan, R. Viswanath, Int. This paper proposes a patterned material composed of two types of photonic crystals based on CdS and SiO 2 nanoparticles. However, the wide range of applications of CdS nanoparticles has incentivized the search for new routes for its synthesis involving both low energy consuming processes and reduced production of toxic by-products. A cadmium acetate stock solution was prepared at 10g/L with respect to the ion Cd2+ and sterilized by membrane filtration (pore size: 0.22m); the water used to prepare this solution was oxygen-free water. To illustrate the quality of the fitting, the inset shows the region from 20 to 50 degrees. 6, pp. Activate your 30 day free trialto continue reading. PVP was used as the dispersant that adsorbs the single colloidal particle to form a molecular folium to prevent the particle from coalescing. For the sample grown employing a concentration of 400ppm of the Cd salt, crystal sizes between 10 and 46nm were obtained with and PDI values equal to 21.7nm and 1.2, respectively. Nanoparticles of CdS are usually synthesized in presence of ligands. A. Dumbrava, C. Badea, G. Prodan, and V. Ciupina, Synthesis and characterization of cadmium sulfide obtained at room temperature, Chalcogenide Letters, vol. J. This is an open access article distributed under the. It was reported that nanoparticles injected intravenously into the blood would pass through the right atrium, right ventricle, lungs, left atrium, and into the left ventricle successively [18]. The inset shows representative fitting to the model of direct transitions between parabolic bands along with the experimental spectrum. Figure 6 gives an example of a possible application. Chang, J.H. Figure 4 presents the spectra for the studied samples after smoothing out the experimental spectra. Claudia Martnez-Alonso or Hailin Hu. Therefore, it should be discussed how CdS could enter into the pancreas. For all studied samples, nanoparticles, whose shape was affected by the Cd content in the solution, were observed. Eng. The authors thank Mara Luisa Ramn and Patricia Altuzar for XRD measurements, Gildardo Casarrubias Segura and Oscar Gomez-Daza for technical support in IV instruments and diffused reflectance spectra, respectively. Electron diffraction patterns clearly show that crystalline disorder increases as the employed Cd concentration increases. The presented results suggest that CdS crystal quality may be controlled through the Cd salt concentration employed. And the CdS were prepared 2.5g/L suspension by PBS. Clipping is a handy way to collect important slides you want to go back to later. 284287, 2009. It is worth mentioning that the presence of cubic crystals with dimensions around 1-m was observed in TEM micrographs for the sample grown with 170ppm, not shown here. Electron. XRD and TEM analysis revealed that the nanoparticles have spherical shape and size in the . CdS nanoparticle-decorated covalent triazine-based frameworks (CdS NPs/CTF-1) were controllably synthesized via a facile one-pot solvothermal method. Some basic properties of cadmium sulfide are listed below: The main applications of Cadmium Sulfide is as a pigment. And the CdS were characterized by XRD (D5000, Siemens, Germany), Jeol2010 TEM (Jeol, USA), TGA, and Raman spectrum Luminescence spectrometer (LS55, Perkin Elmer, USA). Because a value of PDI near to 1.0 implies a narrow and monodispersed distribution while higher values are associated with wider and polydispersed distributions, it is inferred that the PSDs obtained by this methodology are monodispersed. It is yellow in color Nair, H. Hu, Sol. 10, 2609 (2010), P.K. 14, pp. 5). The number and weight average of the particle size ( and , resp.) 1). 5). Sci Rep 4(3):113, Yuan Y et al (2009) Biodistribution and fate of nanodiamonds in vivo. In this process, the CdS stimulated Oddis sphincter and triggered function disorder, resulting the CdS enter into the pancreas with bile or duodenum content regurgitation into the pancreas. Part of Springer Nature. Chem. P. Mohanpuria, N. K. Rana, and S. K. Yadav, Biosynthesis of nanoparticles: technological concepts and future applications, Journal of Nanoparticle Research, vol. 42714279, 2011. 2023 Springer Nature Switzerland AG. Fluorescent CdSe/CdS dot-in-rod nanoparticles have attracted considerable interest for fundamental research and potential applications in bioscience and physical science. 69, no. AHP Materials. Where HepG2 cells were treated with different concentrations of Cd, a rapid and transient ROS generation had triggered Cd-induced apoptosis. 3, pp. Hardman R (2006) A toxicologic review of quantum dots: toxicity depends on physicochemical and environmental factors. However, these ligands could act as series resistance in the active layer of solar cells. AuNPs act as the support for the monolayer assembly of CDs. Sci. Jassim, J. Assoc. The results reported until now indicated clearly that CdS nanocrystals were successfully prepared by employing the sulfide gas produced by the biological process of the sulfate reducing action of Desulfovibrio alaskensis 6SR. The whole set of the allowed reflections for the hexagonal CdS crystal can be found in this ring pattern, indicating that the grains in the powders are randomly oriented. . Green, M. and E. Howman. 371373, 1978. By using Fourier transform infrared spectroscopy (FTIR) impurities were observed on the surface of rinsed CdS samples and they had been eliminated after washing by centrifugation. 4, 9 (2010), M. Thambidurai, N. Muthukumarasamy, D. Velauthapillai, C. Lee, J. 8. Kateryna Dubyk, Tatiana Borisova, Alain Geloen, Mayu Tayama, Tomoya Inose, Yoshio Kobayashi, Raja Angamuthu, Ramesh Rajendran & Raj Vairamuthu, Nanoscale Research Letters L. Shi, C. Pei, and Q. Li, Ordered arrays of shape tunable CuInS2 nanostructures, from nanotubes to nano test tubes and nanowires, Nanoscale, vol. In this work, CdS nanoparticles (CdS-n) were synthesized by microwave-assisted solution precipitation method with two different sulfur compounds: thioacetamide (TA) and thiourea (TU). and polydispersity index in sizes (PDI) of the nanoparticles were calculated using a standard procedure [27]. Through this work, it could help doctors alleviate the negative effects of Cd-containing nanoparticles and facilitate comprehensive utility of Cd-containing nanoparticles in medicine. The accumulation of the kidney showed that the CdS could be excreted through the urinary system (Figs. The history of CdS, more recent advances in the chemistry and synthesis of CdS nanostructures, and their application as nanoscale devices in diverse technology areas from electronics to targeted drug delivery is described. 396404, 2011. Silica-coated cadmium sulfide nanoparticles (SiO 2 /CdS) having a jingle-bell structure were prepared via size-selective photoetching and were used as photocatalysts for dehydrogenation of methanol. Nanoparticle Characterization and Application: An Overview P. Heera and S. Shanmugam* PG & Research Department of Biochemistry, Chennai-100, Asan Memorial College of Arts & Science, Tamil Nadu, India *Corresponding author ABSTRACT Introduction Nanotechnology is a modern field of science which plays a dominant role in day to day . Free access to premium services like Tuneln, Mubi and more. The cell lineage disorder, hepatic lobules disappeared, and hydropic degeneration with focal inflammation could be observed from the liver section, and there was a severe hemorrhage phenomenon. 2023 Springer Nature Switzerland AG. ) of 2.2mA/cm2 and a photovoltage (V Enjoy access to millions of ebooks, audiobooks, magazines, and more from Scribd. Through the above experiment, the effect of the exposure dosage of CdS on biochemical indexes were investigated. Moul, L. Chang, C. Thambidurai, R. Vidu, P. Stroeve, J. Now customize the name of a clipboard to store your clips. Chem Res Toxicol 26(5):662673, Li KG et al (2009) Intracellular oxidative stress and cadmium ions release induce cytotoxicity of unmodified cadmium sulfide quantum dots. Green synthesis and characterization of cadmium sulphide nanoparticles from Chlamydomonas reinhardtii and their application as photocatalysts 10071015, 2011. Domingos et al. Crystal data for the cubic and hexagonal phase of CdS. G. Cabrera, R. Prez, J. M. Gmez, A. balos, and D. Cantero, Toxic effects of dissolved heavy metals on Desulfovibrio vulgaris and Desulfovibrio sp. Biosynthesis Of Silver Nanoparticles Using Curcuma Longa And Their Antibacter International journal of pharmacy research and science (IJPRSONLINE), V mn-mcm-41 catalyst for the vapor phase oxidation of o-xylene, V-Mn-MCM-41 catalyst for the vapor phase oxidation of o-xylene, Chemo bio synthesis of silver nanoparticles. Those pathological measurement results were according to the biochemical indexes content changes in serum. Mater. The GSI scan parameters were as follows: Prep Group,30s; scan mode, axial; gantry rotation speed, 0.5s/circle; tube voltage, 140 and 80kV; tube current, 630mAs; detector coverage,20mm;30%ASIR; matrix size,512; slice thickness, 0.625mm. AHP Materials. The inset of Figure 2 shows representative X-ray diffractogram obtained by the Rietveld refinement for the sample grown with 400ppm of the Cd salt; the continuous line corresponds to the experimental data, and circles symbols represent the calculated intensity obtained from the adjustment. 20, pp. A possible explanation for the absence of quantum confinement effects could be that there is no capping material acting as confining barrier. Phys. The best cell prepared with CdS nanoparticles showed a photocurrent (J Martnez-Alonso, C., Cortina-Marrero, H.J., Selene Coria-Monroy, C. et al. The section of the lung tissue showed bronchial epithelial disorder and alveolar walls broken with a severe bleeding, in addition, the brown stain of section indicated that there were a lot of nanoparticles in the lung tissues. But most of the iodine-containing compounds existed various defects, such as difficult to synthesize, non-targeting, and rapid metabolism. 2011, Article ID 270974, 16 pages, 2011. CdS was obtained by centrifugation at 5000rpm for 15min; the powder was washed with a solution of acetone-water (4:1) following centrifugation at 5000rpm for 5min. And so, there was a high uptake of CdS in the pancreas (Fig. Instant access to millions of ebooks, audiobooks, magazines, podcasts and more. With the development of science and technology, new applications about nanoparticles should be explored to achieve full-scale knowledge. 129, 4136 (2007), H. Cortina, E. Pineda, J. Campos, M.E. 17, 2013. In agreement with XRD results, TEM micrographs show a mixture of cubic and hexagonal phases for the whole set of samples studied. Kotkata, A.E. By using the Scherrers equation d=0.8/cos, where is the wavelength of the X-ray radiation, is the full width at half maximum (FWHM) of the (111) peak, and is the angle of diffraction, the average size of the CdS nanoparticles was determined to be of the order of 3nm. 5, pp. [13] synthesized highly stable and surface-protected CdS induced apoptotic cell death by selectively generating excess ROS in human prostate cancer lymph node carcinoma of the prostate (LNCaP) cells. The use of nanoparticles in pharmaceutical applications has many benefits.. The peak at 430cm1 is observed for the sample grown with the lowest salt content, but its strength decreased until it practically disappeared for the 400ppm sample. All used reagents were of analytical grade and were obtained from Sigma-Aldrich company. The raw CdS were purchased from Shanghai Biological Technology Co., Ltd, with particle size about 130nm. Soc. Human tissue is permeable to near infra-red light. As well known, the liver and spleen were the immune organs of biology body with a lot of macrophages (e.g., Kupffer cells); hence, CdS as the invasive materials for biology body were captured by RES in the liver and spleen with a mass of phagocytes, resulting in high uptake of the liver and spleen (Fig. X-ray diffraction (XRD) patterns indicate that the obtained products were of hexagonal structure. The splenic sinus eclasis, size disorder of follicular, hyperplasia of extramedullary hematopoietic giant cells, and serious hemorrhage phenomenon could be seen from the spleen section. Cadmium sulfide is a chemical compound that has the formula CdS. S.-G. Hur, E.-T. Kim, J.-H. Lee, G.-H. Kim, and S.-G. Yoon, Characterization of photoconductive CdS thin films prepared on glass substrates for photoconductive-sensor applications, Journal of Vacuum Science & Technology B, vol. 100, no. [3] examined the toxicity effects of CdS-engineered nanoparticles compared to soluble Cd, on marine ragworms exposed for 14days to these contaminants (10g Cd L1) in seawater or via food, and they pointed out oxidative processes as the main consequences of exposure to Cd-based NPs in worms. Figure 1. Nicho, H. Hu, Eur. Therefore, there may be a need to customize the extraction conditions. The highest structural quality is obtained using lower concentrations of the Cd salt. The used software was the Powder Cell software V. 2.4. 10, pp. And the following investigations showed that the raw CdS could damage the tissues accumulating nanoparticles. 100, 13226 (1996), M. Zhong, D. Yang, J. Zhang, J. Shi, X. Wang, C. Li, Sol. Cadmium sulfide (CdS) nanoparticles were synthesized by chemical precipitation method using cadmium chloride (CdCl2), sodium sulfide (Na2S) and water as a solvent by varying temperatures from 20-80 degrees C. The nanoparticles were characterized by X-ray diffraction (XRD), Raman spectroscopy, field Do not sell or share my personal information, 1. However, theoretical developments are needed to produce models that take into account crystal imperfections [34, 35]. Environ Health Perspect 114(2):165172, Article Electron. One of the advantages of CdS is that even the material produced with low crystalline quality is useful in the massive production of low cost photovoltaic devices. In it the hemimorphic character is easily seen because the top of the crystal is the point and the bottom of it is its base. The detailed analysis of the growth process of the crystals is far from the scope of this work but it is clear that shape evolution is influenced both by the amount of Cd ions available for the formation of CdS and the lack of spatial restrictions during crystal growth. 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